Diphosphite ligands derived from carbohydrates as stabilizers for ruthenium nanoparticles: promising catalytic systems in arene hydrogenation.
نویسندگان
چکیده
Ruthenium nanoparticles (RuNPs) were prepared through the hydrogenation of [Ru(COD)(COT)] (COD = 1,5-cyclooctadiene, COT = 1,3,5-cyclooctatriene) in the presence of diphosphites derived from carbohydrates as stabilizing agents, and interestingly, structural modifications of the diphosphite backbone were found to influence nanoparticle size and dispersity, as well as their catalytic activity in arene hydrogenation.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 24 شماره
صفحات -
تاریخ انتشار 2008